Match the following allotropes of carbon with their standard enthalpy of formation $(\Delta_f H^{\Theta})$:
Allotrope$\Delta_f H^{\Theta}$
$i$. Graphite$b$. $0 \ kJ/mol$
$ii$. Diamond$c$. $1.90 \ kJ/mol$
$iii$. Fullerene$a$. $38.1 \ kJ/mol$

  • A
    $i-b, ii-c, iii-a$
  • B
    $i-c, ii-b, iii-a$
  • C
    $i-a, ii-b, iii-c$
  • D
    $i-b, ii-a, iii-c$

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What is the value of $\Delta H^{\circ}$ for the formation of ethanol from ethene gas and liquid water from the following data (in $kJ$)?
$(i)$ $C_2H_5OH_{(l)} + 3O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + 3H_2O_{(l)}$ $\Delta H^{\circ} = -1368 \ kJ$
$(ii)$ $C_2H_{4_{(g)}} + 3O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + 2H_2O_{(l)}$ $\Delta H^{\circ} = -1410 \ kJ$

Given two processes:
$\frac{1}{2} P_{4(s)} + 3 Cl_{2(g)} \to 2 PCl_{3(l)} \;; \Delta H = -635 \ kJ$
$PCl_{3(l)} + Cl_{2(g)} \to PCl_{5(s)} \;; \Delta H = -137 \ kJ$
The value of the heat of formation of $PCl_{5(s)}$ is ...... $kJ \ mol^{-1}$.

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$A$,$B$,$C$ and $D$ are some compounds. The enthalpy of formation of $A_{(g)}$,$B_{(g)}$,$C_{(g)}$ and $D_{(g)}$ is $9.7, -110, 81$ and $-393 \ kJ \ mol^{-1}$ respectively. What is $\Delta_r H$ (in $kJ \ mol^{-1}$) for the given reaction?
$A_{(g)} + 3B_{(g)} \longrightarrow C_{(g)} + 3D_{(g)}$

Given the following data:
Reaction Energy Change (in $kJ$)
$Li_{(s)} \to Li_{(g)}$ $161$
$Li_{(g)} \to Li^{+}_{(g)}$ $520$
$\frac{1}{2} F_{2(g)} \to F_{(g)}$ $77$
$F_{(g)} + e^- \to F^{-}_{(g)}$ (Electron gain enthalpy)
$Li^{+}_{(g)} + F^{-}_{(g)} \to LiF_{(s)}$ $-1047$
$Li_{(s)} + \frac{1}{2} F_{2(g)} \to LiF_{(s)}$ $-617$

Based on the data provided,the value of electron gain enthalpy of fluorine would be $kJ\ mol^{-1}$.

The bond energies of $H-H$ and $Cl-Cl$ are $430 \, kJ \, mol^{-1}$ and $242 \, kJ \, mol^{-1}$ respectively. $\Delta H_f$ for $HCl$ is $-91 \, kJ \, mol^{-1}$. The bond energy of $HCl$ will be ............. $kJ \, mol^{-1}$.

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